Grupo de Ingeniería Química y Ambiental

Influence on properties and phase structure of single gas-phase reactor made impact polypropylene copolymers

Pastor-García, M. T.; Suárez, I.; Expósito, M. T.; Coto B.; García-Muñoz, R. A.

Molecular structure and local dynamic in impact polypropylene copolymers studied by preparative TREF, solid state NMR spectroscopy, and SFM microscopy

Fernández, A.; Expósito, M. T.; Peña, B.; Berger, R.; Shu, J.; Graf, R.; Spiess, H. W.; García-Muñoz, R. A.

Microstructure and properties of branched polyethylene: Application of a three-phase structural model

Martín, S.; Expósito, M. T.; Vega, J. F.; Martínez-Salazar, J.

Molecular characterization of polypropylene heterophasic copolymers by fractionation techniques

García, R. A.; Coto, B.; Expósito, M. T.; Suarez, I.; Fernández-Fernández, A.; Caveda, S.

Eliminating sharkskin distortion in polyethylene extrusion via a molecular route

Vega, J. F.; Expósito, M. T.; Otegui, J.; Martínez-Salazar, J.

Molecular structure and rheology of homogeneous ethylene-co-styrene polymers

Vega, J. F.; Expósito, M. T.; Martínez-Salazar, J.; Lobón-Poo, M.; Osío Barcina, J.; García Martínez, A.; Reyes, M. L.

A three-phase microstructural model to explain the mechanical relaxations of branched polyethylene: a DSC, WAXD and DMTA combined study

Martín, S. ; Vega, J.F., Expósito, M.T.; Flores, A.; Martínez-Salazar, J.

Structure and physical properties of polyethylenes obtained from dual catalysis process

Vega, J. F.; Otegui, J.; Expósito, M. T.; Martín, C.; Prieto, O.; Martínez-Salazar, J.

  • Polymer Bulletin, 60, 331-342 (2008)

Highly active ethylene/hydroxyl comonomers copolymerization using metallocene catalyst

Expósito, M. T.; Vega, J. F.; Ramos, J.; Osío-Barcina, J.; García-Martínez, A.; Martín, C.; Martínez-Salazar, J.

  • Journal of Applied Polymer Science, 109, 1529-1534 (2008)

Entanglement network and relaxation temperature dependence of single-site catalyzed ethylene/1-hexene copolymers

Vega, J. F.; Martín, S.; Expósito, M. T.; Martínez-Salazar, J.

  • Journal of Applied Polymer Science, 109 (3), 1564-1569 (2008)

Molecular structure and properties of ethylene-co-styrene polymers obtained from [norbornane-7,7-bis(indenil)]titanium dichloride catalyst system

Expósito, M. T.; Vega, J. F.; Martínez-Salazar, J.

  • Journal of Applied Polymer Science, 106, 1421-1430 (2007)

Meso-[norbornane-7,7-bis(indenyl)]titanium dichloride: a highly active catalyst for ethylene-styrene copolymerization

García Martínez, A.; Osío Barcina, J.; Lobón, M.; Expósito, M. T.; Vega, J. F.; López, M.; Martínez-Salazar, J.

  • Macromolecules, 39, 7479-7482 (2006)

Synthesis and properties of ethylene/styrene copolymers produced by metallocene catalysts

Haider, N.; Expósito, M. T.; Muñoz-Escalona, A.; Ramos, J.; Vega, J. F.; Méndez, L.; Martínez-Salazar, J.

  • Journal of Applied Polymer Science, 102, 3420-3429 (2006)

An experimental and computational evaluation of ethylene/styrene copolymerisation using a homogeneous single-site titanium (IV)-constrained geometry catalyst

Martínez, S.;Expósito, M. T.;Ramos, J.; Cruz, V.; Martínez, M. C.; Muñoz-Escalona, A.; Martínez-Salazar, J.

  • Journal of Polymer Science, Part A: Polymer Chemistry, 43, 711-725 (2005)

Ethylene/styrene copolymerization by homogeneous metallocene catalysts: experimental and molecular simulations using rac- ethylenebis-(tetrahydroindenyl)MCl2 M=[Ti, Zr] systems

Expósito, M. T.; Martínez, S.; Ramos, J.; Cruz, V.; López, M.; Muñoz-Escalona, A.; Haider, N.; Martínez-Salazar, J.

  • Polymer, 45, 9029-9038 (2004)

The elimination of extrudate distorsions in metallocene-catalyzed polyethylene

Aguilar, M.; Expósito, M.T.; Vega, J.F.; Muñoz-Escalona, A.;Martínez-Salazar, J.

  • Macromolecules, 37(3), 681-683 (2004)

Synthesis, structure and reactivity of new late transition metal complexes bearing diphosphane ligands derived from bis(pyrazol-1-yl)methane

Otero, A.; Carrillo-Hermosilla, F.; Terreros, P.; Expósito, T.; Rojas, S.; Fernández-Baeza, J.; Antiñolo, A.; López-Solera, I.

  • European Journal of Inorganic Chemistry, 3233-3241 (2003)

Niobium complexes containing a new chiral heteroescorpionate ligand and its reactivity with O2 to give the first gem-diolate niobium complexes

Otero, A.; Fernández-Baeza, J.; Antiñolo, A.; Tejeda, J.; Lara-Sánchez, A.; Sánchez-Barba, L.; Expósito, M. T.; Rodríguez, A.M.

  • Journal of Chemical Society, 1614-1619 (2003)

Synthesis and electrochemistry of niobium complexes incorporating asymmetrically substituted ansa-ligands

Antiñolo, A.; Expósito, T.; del Hierro, I.; Lucas, D.; Mugnier, Y.;Orive, I.; Otero, A.; Prashar, S.

  • J. Organomet. Chem., 665, 63-69 (2002)